Acids, Bases & Salts
Comprehensive Mastery Guide for NEET Aspirants
Willer Select Advantage
This specially curated content is part of Willer Academy's NEET 2027 Strategic Preparation Program, designed by our expert faculty and AI-powered learning systems to give you a competitive edge.
Programmer Note: Willer Select students receive customized learning paths with this material optimized for NEET 2027 preparation, including spaced repetition scheduling and competency mapping.
I. Foundational Concepts
1. Acids
Definition: Substances that release hydrogen ions (H⁺) in aqueous solutions.
Key Properties:
- Sour taste (e.g., lemon, vinegar)
- Turn blue litmus → red
- Conduct electricity (due to mobile H⁺ ions)
- React with active metals to release H₂ gas
NEET Focus
Arrhenius Theory: Acids increase H⁺ concentration in water.
Medical Connection: Stomach acid (HCl) helps digestion but excess causes acidity (treated with antacids).
2. Bases
Definition: Substances that release hydroxide ions (OH⁻) in water.
Key Properties:
- Bitter taste, soapy feel
- Turn red litmus → blue
- Conduct electricity (due to OH⁻ ions)
Teaching Demonstration
Test soap solution (pH ~10) with litmus paper to show base properties.
3. Salts
Definition: Ionic compounds formed by neutralization reactions (acid + base).
NEET Relevance: Salt balance crucial in human physiology (electrolytes).
II. Core Theory & Mechanisms
1. pH Scale (0-14)
Measures H⁺ ion concentration:
- pH < 7: Acidic (higher H⁺ concentration)
- pH = 7: Neutral (pure water at 25°C)
- pH > 7: Basic (higher OH⁻ concentration)
Classroom Activity
Use pH strips to test various substances:
| Substance | pH | Nature |
|---|---|---|
| Gastric juice | 1.5-2.0 | Strongly acidic |
| Blood | 7.35-7.45 | Slightly basic |
| Pancreatic fluid | 8.1-8.3 | Basic |
2. Neutralization Reactions
Medical Application
Antacids like Mg(OH)₂ neutralize excess stomach acid:
3. Metal-Acid Reactions
Redox Mechanism
Oxidation: Zn → Zn²⁺ + 2e⁻
Reduction: 2H⁺ + 2e⁻ → H₂↑
III. Industrial Processes (NEET Weightage)
1. Chlor-Alkali Process (NaOH Production)
| Electrode | Reaction | Product |
|---|---|---|
| Anode (+ve) | 2Cl⁻ → Cl₂ + 2e⁻ | Chlorine gas |
| Cathode (-ve) | 2H₂O + 2e⁻ → H₂ + 2OH⁻ | Hydrogen gas + NaOH |
NEET Trick
Remember: "A Cat Has No Clothes" for electrode products:
- Anode → Cl₂
- Cathode → H₂ + NaOH
2. Bleaching Powder (CaOCl₂)
Active Component: Hypochlorite ion (ClO⁻) acts as oxidizing agent.
IV. Willer Select NEET Optimization
For Willer Select Programmers
This content is tagged with:
- NEET 2027 competency codes: C3.1 (Acid-Base), C3.2 (Salts)
- Difficulty levels: Basic (70%), Moderate (25%), Advanced (5%)
- Recommended spaced repetition intervals: 1d, 7d, 30d
NEET Previous Year Questions Analysis
2022 Question: "Why doesn't dry HCl change litmus color?"
Key Concept: H⁺ ions are produced only in aqueous solution.
2021 Question: "Which salt is used in antacids?"
Answer: Sodium bicarbonate (NaHCO₃) or magnesium hydroxide [Mg(OH)₂].
Willer Memory Technique
"POP Goes the Bone":
- Plaster of Paris (CaSO₄·½H₂O) used for bone fractures
Willer Select NEET 2027 Roadmap
This content is part of our 3-Year NEET Preparation Program:
| Year | Focus | Acids-Bases Milestone |
|---|---|---|
| 2024-25 | Concept Building | Mastery of basic reactions |
| 2025-26 | Application | Medical applications |
| 2026-27 | NEET Optimization | PYQ analysis & speed drills |
Faculty Note
Willer Select students receive additional:
- Monthly competency assessments
- Personalized doubt-clearing sessions
- AI-generated practice tests
Acids, Bases & Salts - CBSE Class 10
Comprehensive Question Bank with Solutions
I. Indicators (5 Markers)
| Indicator | Acid (pH < 7) | Base (pH > 7) | NEET Connection |
|---|---|---|---|
| Litmus | Red | Blue | Diagnostic tests |
| Phenolphthalein | Colorless | Pink | Titration experiments |
| Methyl Orange | Red | Yellow | Gastric pH analysis |
| Turmeric | Yellow | Reddish-brown | Natural pH detector |
CBSE Practical Question:
Q: A student observes that onion smell vanishes when added to solution X but remains in solution Y. Identify X and Y.
A: X = Base (e.g., NaOH), Y = Acid (e.g., HCl). Onion is an olfactory indicator.
II. MCQs (20 Questions)
1. Which acid is present in ant sting?
2. The pH of a solution decreases from 7 to 2. This means:
20. Plaster of Paris hardens by:
III. Assertion-Reasoning (5 Questions)
1. Assertion (A): Dry HCl gas doesn't change the color of litmus paper.
Reason (R): H⁺ ions are produced only in aqueous solution.
Answer: Both A and R are true, and R explains A.
2. Assertion (A): Sodium carbonate is called washing soda.
Reason (R): It is used for water softening.
Answer: Both A and R are true, but R doesn't explain A.
5. Assertion (A): Antacids contain bases like Mg(OH)₂.
Reason (R): They neutralize excess stomach acid.
Answer: Both A and R are true, and R explains A.
IV. Practical-Based Questions (10 Marks)
Experiment 1: Neutralization Reaction
Procedure:
- Take 10ml dilute NaOH in a conical flask
- Add 2 drops phenolphthalein (turns pink)
- Add dilute HCl dropwise until color disappears
Observation: Pink → colorless (endpoint reached)
Precaution: Swirl the flask continuously
Experiment 2: Metal-Acid Reaction
Question: Why does copper not react with dilute HCl?
Answer: Copper is below hydrogen in reactivity series.
V. Previous Year CBSE Questions (2020-2024)
2024 Q: Which salt is used in fire extinguishers?
Answer: Sodium bicarbonate (NaHCO₃)
2023 Q: Name the acid present in tamarind.
Answer: Tartaric acid
2022 Q: What happens when Plaster of Paris mixes with water?
Answer: Hardens to form gypsum (CaSO₄·2H₂O)
Willer Select NEET 2027 Special
Competency Mapping
| Topic | CBSE Marks | NEET Relevance |
|---|---|---|
| pH Concept | 3 | Blood pH regulation |
| Salt Preparation | 4 | Medicinal salts |
AI-Powered Analysis
Willer Select students receive:
- Personalized question recommendations
- Difficulty-adjusted practice sets
- Performance analytics dashboard
Class 10 Chemistry: Acids, Bases and Salts
Complete Question Bank with Answers
Short Answer Questions (2 Marks Each)
1. Why does dry HCl gas not change the color of dry litmus paper?
Dry HCl gas doesn't contain free H⁺ ions. Litmus changes color only in the presence of H⁺ ions which are formed when HCl dissolves in water (HCl + H₂O → H₃O⁺ + Cl⁻).
2. What happens when Plaster of Paris is mixed with water?
Plaster of Paris (CaSO₄·½H₂O) reacts with water to form gypsum (CaSO₄·2H₂O) and hardens:
CaSO₄·½H₂O + 1½H₂O → CaSO₄·2H₂O
This hardening property makes it useful for making casts, sculptures, and wall plasters.
3. Name the acid present in ant sting and give its chemical formula.
Formic acid (Methanoic acid), Chemical formula: HCOOH
It causes irritation and burning sensation when ants bite. Rubbing baking soda (a base) neutralizes the effect.
4. Why is sodium hydrogen carbonate used as an antacid?
Sodium hydrogen carbonate (NaHCO₃) is a mild base that neutralizes excess stomach acid (HCl):
NaHCO₃ + HCl → NaCl + H₂O + CO₂
It provides quick relief from acidity and heartburn.
5. What is the chemical name and formula of bleaching powder?
Chemical name: Calcium oxychloride
Formula: CaOCl₂
It is produced by the reaction: Ca(OH)₂ + Cl₂ → CaOCl₂ + H₂O
6. Why does distilled water not conduct electricity?
Distilled water lacks ions (H⁺ and OH⁻) in sufficient concentration to conduct electricity. Pure water has very low dissociation (H₂O ⇌ H⁺ + OH⁻) with only 1×10⁻⁷ M of each ion at 25°C.
7. What is the pH range of acidic, basic and neutral solutions?
- Acidic solutions: pH < 7
- Neutral solutions: pH = 7
- Basic solutions: pH > 7
The pH scale ranges from 0 (most acidic) to 14 (most basic).
8. Give two examples of olfactory indicators.
- Onion: Smell disappears in basic solution but remains in acidic solution
- Vanilla: Smell disappears in basic solution but remains in acidic solution
These indicators change their smell in acidic or basic media.
9. What happens when carbon dioxide is passed through lime water?
When CO₂ is passed through lime water [Ca(OH)₂], it turns milky due to formation of insoluble calcium carbonate:
Ca(OH)₂ + CO₂ → CaCO₃↓ + H₂O
With excess CO₂, the milkiness disappears as soluble calcium bicarbonate forms:
CaCO₃ + H₂O + CO₂ → Ca(HCO₃)₂
10. Why do acids not show acidic behavior in absence of water?
Acids show acidic behavior only when H⁺ ions are released, which requires water. In absence of water:
- Acids remain in molecular form (e.g., HCl as molecules)
- No free H⁺ ions are available to show acidic properties
- Water helps in ionization: HCl + H₂O → H₃O⁺ + Cl⁻
Assertion-Reasoning Questions (3 Marks Each)
1. Assertion (A): Sodium hydroxide is called caustic soda.
Reason (R): It is highly corrosive and can cause severe burns.
Answer: Both A and R are true and R is the correct explanation of A.
Explanation: NaOH is called caustic soda because of its highly corrosive nature that can burn skin and other tissues. The term "caustic" refers to its ability to corrode or burn organic matter.
2. Assertion (A): Baking soda is used in fire extinguishers.
Reason (R): It decomposes to produce carbon dioxide gas when heated.
Answer: Both A and R are true and R is the correct explanation of A.
Explanation: Baking soda (NaHCO₃) decomposes when heated to produce CO₂ gas which helps in extinguishing fires by cutting off oxygen supply:
2NaHCO₃ → Na₂CO₃ + H₂O + CO₂
3. Assertion (A): Tooth decay starts when pH of mouth falls below 5.5.
Reason (R): Acid produced by bacteria dissolves calcium phosphate of tooth enamel.
Answer: Both A and R are true and R is the correct explanation of A.
Explanation: Bacteria in mouth produce acids (pH < 5.5) by fermentation of food particles. These acids react with calcium phosphate [Ca₃(PO₄)₂] of enamel causing tooth decay.
4. Assertion (A): Copper does not react with dilute hydrochloric acid.
Reason (R): Copper is below hydrogen in the reactivity series.
Answer: Both A and R are true and R is the correct explanation of A.
Explanation: Metals below hydrogen in reactivity series cannot displace hydrogen from acids. Copper (Cu) being less reactive than hydrogen doesn't react with dilute HCl.
5. Assertion (A): Farmers add slaked lime to acidic soils.
Reason (R): Slaked lime is a base that neutralizes soil acidity.
Answer: Both A and R are true and R is the correct explanation of A.
Explanation: Slaked lime [Ca(OH)₂] is added to acidic soils to neutralize excess acids and bring pH to optimal level (6-7) for plant growth:
Ca(OH)₂ + 2H⁺ → Ca²⁺ + 2H₂O
Long Answer Questions (5 Marks Each)
1. Explain the chlor-alkali process with labeled diagram. Write chemical equations involved and mention two uses of each product.
Chlor-alkali Process: Electrolysis of concentrated NaCl solution (brine)
Process Description:
- Concentrated NaCl solution is electrolyzed using inert electrodes
- Chlorine gas is produced at anode
- Hydrogen gas at cathode
- Sodium hydroxide solution forms near cathode
Chemical Equations:
At anode (Oxidation): 2Cl⁻ → Cl₂ + 2e⁻
At cathode (Reduction): 2H₂O + 2e⁻ → H₂ + 2OH⁻
Overall reaction: 2NaCl + 2H₂O → 2NaOH + Cl₂ + H₂
Uses of Products:
| Product | Uses |
|---|---|
| Chlorine (Cl₂) |
|
| Hydrogen (H₂) |
|
| Sodium hydroxide (NaOH) |
|
2. What is pH scale? How is it significant in everyday life? Give three examples.
pH Scale: A logarithmic scale (0-14) that measures hydrogen ion concentration in a solution:
pH = -log[H⁺]
Where [H⁺] is hydrogen ion concentration in moles per liter
Significance in Daily Life:
- Digestive System:
- Stomach pH ~1.5 (HCl) helps activate pepsin enzyme for protein digestion
- Heartburn occurs when stomach acid refluxes into esophagus (pH ~6-7)
- Tooth Care:
- Tooth enamel (calcium phosphate) dissolves at pH < 5.5
- Bacteria produce acids from food debris, lowering mouth pH
- Toothpaste is basic (pH ~8) to neutralize acids
- Agriculture:
- Most crops grow best in soil pH 6-7
- Acidic soils (pH < 5) are treated with lime [Ca(OH)₂]
- Basic soils (pH > 8) are treated with organic matter
- Blood pH:
- Maintained at 7.35-7.45 for proper enzyme function
- pH < 7.35 (acidosis) or > 7.45 (alkalosis) can be life-threatening
3. Describe the preparation, properties and uses of baking soda. Write chemical equations involved.
Preparation of Baking Soda (NaHCO₃):
Produced by Solvay process:
NaCl + NH₃ + CO₂ + H₂O → NaHCO₃ + NH₄Cl
Properties:
- White crystalline solid
- Mildly alkaline (pH ~8.4)
- Decomposes on heating: 2NaHCO₃ → Na₂CO₃ + H₂O + CO₂
- Reacts with acids: NaHCO₃ + HCl → NaCl + H₂O + CO₂
Uses:
- Antacid: Neutralizes excess stomach acid
- Baking: Produces CO₂ making cakes fluffy
- Fire Extinguisher: Releases CO₂ which smothers fires
- Cleaning Agent: Mild abrasive and deodorizer
- Preparation of baking powder: Mixed with tartaric acid
4. Explain how acids and bases are identified using (a) litmus paper (b) phenolphthalein (c) methyl orange. Give color changes observed.
Indicator Tests:
| Indicator | Acid | Base | Neutral |
|---|---|---|---|
| Litmus paper | Blue → Red | Red → Blue | No change (purple) |
| Phenolphthalein | Colorless | Colorless → Pink | Colorless |
| Methyl orange | Red | Yellow | Orange |
Mechanism:
- Litmus: Weak acid that changes structure at different pH
- Phenolphthalein: Colorless in acid (pH < 8.3), pink in base (pH > 10)
- Methyl orange: Red at pH < 3.1, yellow at pH > 4.4
Practical Applications:
- Litmus: Quick acid/base test
- Phenolphthalein: Used in strong acid-strong base titrations
- Methyl orange: Used in weak base-strong acid titrations
5. Differentiate between acids and bases with three properties each. Give two examples of each that you use in daily life.
Differences:
| Property | Acids | Bases |
|---|---|---|
| Taste | Sour (e.g., lemon) | Bitter (e.g., baking soda) |
| Touch | No characteristic feel | Soapy/slippery |
| Litmus Test | Blue → Red | Red → Blue |
| pH | < 7 | > 7 |
| Reaction with metals | Produce H₂ gas | No reaction (except Al, Zn) |
Daily Life Examples:
| Acids | Bases |
|---|---|
|
|
Neutralization Reaction Example:
HCl + NaOH → NaCl + H₂O
(Stomach acid) + (Antacid) → (Salt) + (Water)
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